centralize — To centralize a country, state, or organization means to create a system in which one central group of people gives instructions to regional groups.
deputize — If you deputize for someone, you do something on their behalf, for example attend a meeting.
empathize — Understand and share the feelings of another.
emphasize — Give special importance or prominence to (something) in speaking or writing.
decentralize — To decentralize government or a large organization means to move some departments away from the main administrative area, or to give more power to local departments.
desensitize — To desensitize someone to things such as pain, anxiety, or other people's suffering, means to cause them to react less strongly to them.
exemplified — Simple past tense and past participle of exemplify.
federalize — to bring under the control of a federal government: to federalize the National Guard.
Four-or-more syllable rhymes
compartmentalize — To compartmentalize something means to divide it into separate sections.